Product ID:PURGEABLES HALOCARBON MIXTURE, 48747
MSDS Date:09/09/1993
FSC:6630
NIIN:00N064300
MSDS Number: BZRFK

SUPELCO INC

SUPELCO PARK
BELLEFONTE, PA 16823-0048
US

Emergency Phone: 814-359-3441

Info Phone: 814-359-3441

Cage: 54968

SIGMA-ALDRICH INC.

14508 ST. LOUIS, MO 63103 US

Telephone: 314-771-5765/414-273-3850X5996

Cage: 54968

BENZENE, CHLORO-; (CHLOROBENZENE) (SARA 313) (CERCLA). LD50

CAS: 108-90-7

RTECS: CZ0175000

Fraction By Weight: 0.06%

OSHA PEL 75 PPM

ACGIH TLV: 10 PPM

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

ETHANE, 1,2-DICHLORO-; (SARA 313) (CERCLA) LD50 (ORAL RAT)

CAS: 107-06-2

RTECS: KI0525000

Fraction By Weight: 0.06%

OSHA PEL 50 PPM; Z-2

ACGIH TLV: 10 PPM

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

ETHANE,1,1,1-TRICHLORO- (SARA 313) (CERCLA) LD50 (ORAL

CAS: 71-55-6

RTECS: KJ2975000

Fraction By Weight: 0.06%

OSHA PEL 350 PPM

ACGIH TLV: 350 PPM/450STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

ETHANE, 1,1-DICHLORO-; (SARA 313) (CERCLA) LD50 (ORAL RAT)

CAS: 75-34-3

RTECS: KI0175000

Fraction By Weight: 0.012%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

ETHANE,1,1,2-TRICHLORO- (SARA 313) (CERCLA) LD50 (ORAL

CAS: 79-00-5

RTECS: KJ3150000

Fraction By Weight: 0.012%

OSHA PEL 10 PPM, S

ACGIH TLV: 10 PPM, S

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

ETHANE,1,1,2,2-TETRACHLORO- (SARA 313) (CERCLA)

CAS: 79-34-5

RTECS: KI8575000

Fraction By Weight: 0.012%

OSHA PEL 5 PPM, S

ACGIH TLV: 1 PPM, S

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

BENZENE, O-DICHLORO-; (BENZENE, 1,2-DICHLORO-)(SARA 313)

CAS: 95-50-1

RTECS: CZ4500000

Fraction By Weight: 0.012%

OSHA PEL C 50 PPM

ACGIH TLV: 25 PPM/50 STEL

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

BENZENE, M-CHLORO-;(BENZENE, 1,3-DICHLORO-) (SARA 313)

CAS: 541-73-1

RTECS: CZ4499000

Fraction By Weight: 0.012%

OSHA PEL N/K

ACGIH TLV: N/K

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

BENZENE, P-DICHLORO-; (1,4-DICHLOROBENZENE) (SARA 313)

CAS: 106-46-7

RTECS: CZ4550000

Fraction By Weight: 0.012%

OSHA PEL 75 PPM

ACGIH TLV: 10 PPM, A3

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

ETHYLENE, 1,1-DICHLORO-; (1,1-DICHLOROETHYLENE) (CERCLA)

CAS: 75-35-4

RTECS: KV9275000

Fraction By Weight: 0.024%

OSHA PEL 1 PPM

ACGIH TLV: 5 PPM/20 STEL

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

ETHYLENE, 1,2-DICHLORO-, (E)- (SARA 313) (CERCLA) LD50

CAS: 156-60-5

RTECS: KV9400000

Fraction By Weight: 0.06%

OSHA PEL 200 PPM (MFR)

ACGIH TLV: 200 PPM (MFR)

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

PROPANE, 1,2-DICHLORO- (SARA 313) (CERCLA) LD50 (ORAL RAT)

CAS: 78-87-5

RTECS: TX9625000

Fraction By Weight: 0.012%

OSHA PEL 75 PPM

ACGIH TLV: 75 PPM/110STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

PROPENE,1,3-DICHLORO-; (1,3-DICHLOROPROPANE, MIX OF ISOMERS

CAS: 542-75-6

RTECS: UC8310000

Fraction By Weight: 0.012%

OSHA PEL 1 PPM, S

ACGIH TLV: 1 PPM, S

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

ETHYLENE, TETRACHLORO- (SARA 313) (CERCLA) LD50 (ORAL RAT)

CAS: 127-18-4

RTECS: KX3850000

Fraction By Weight: 0.012%

OSHA PEL 100 PPM, Z-2

ACGIH TLV: 25PPM/100STEL, A3

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

ETHYLENE, TRICHLORO- (SARA 313) (CERCLA) LD50 (ORAL RAT)

CAS: 79-01-6

RTECS: KX4550000

Fraction By Weight: 0.012%

OSHA PEL 100 PPM; Z-2

ACGIH TLV: 50 PPM/100STEL, A5

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

METHYL ALCOHOL; (METHANOL) (SARA 313) (CERCLA) LD50 (ORAL

CAS: 67-56-1

RTECS: PC1400000

Fraction By Weight: 99.592%

OSHA PEL 200 PPM, S

ACGIH TLV: 200PPM/250STEL, S

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

CARBON TETRACHLORIDE; (METHANE, TETRACHLORO-) (SARA 313)

CAS: 56-23-5

RTECS: FG4900000

Fraction By Weight: 0.012%

OSHA PEL 10 PPM Z-2

ACGIH TLV: 5PPM/10 STEL, A3, S

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

METHANE, DICHLORO- (SARA 313) (CERCLA) LD50 (ORAL RAT)

CAS: 75-09-2

RTECS: PA8050000

Fraction By Weight: 0.012%

OSHA PEL 500 PPM; Z-2

ACGIH TLV: 50 PPM, A2

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

LD50 LC50 Mixture:SEE INGREDIENTS SECTION.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: HARMFUL IF INHALED. MAY BE
FATAL IF SWALLOWED. CAUSES HEADACHE, NAUSEA, GI DISTURBANCES,
BLINDNESS. CHLOROCARBON MATERIALS HAVE PRODUCED SENSITIZATION OF
THE MYOCARDIUM TO EPINEPHRINE IN LABORA TORY ANIMALS AND COULD HAVE
A SIMILAR EFFECT IN HUMANS. ADRENOMIMETICS (E.G.,EPINEPHRINE) MAY
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: BE CONTRAINDICATED EXCEPT FOR
LIFE-SUSTAINING USES IN HUMANS ACUTELY OR CHRONICALLY EXPOSED TO
CHLOROCARBONS . CNTNS LOW CONCS OF MATLS KNOWN TO STATE OF
CALIORNIA TO CAUSE CANCER. SUC H CONCS ARE SUBSTANTIALLY BELOW
OSHA-HCS THRESHOLDS WHICH WOULD REQ LISTING HEREIN AS A COMPONENT
OF THIS MIXTURE.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYE: FLUSH W/WATER FOR AT LEAST 15 MIN. CONT MD. SKIN: FLUSH
W/LGE VOL OF WATER. INHAL: IMMED MOVE TO FRESH AIR. IF BRTHG STOPS,
GIVE ARTF RESP. CONT MD. INGEST: NEVER GIVE ANYTHING BY MOUTH TO AN
UNC ON PERS. NEVER TRY TO MAKE AN UNCON PERS VOMIT. GIVE 2
TABLESPOONS OF BAKING SODA IN GLASS OF WATER. PRESS FINGER TO BACK
OF TONGUE TO INDUCE VOMIT. IMMED CONT MD.

Flash Point:50.0F,10.0C
Lower Limits:6.0%
Upper Limits:36.0%
Extinguishing Media:USE CARBON DIOXIDE, DRY CHEMICAL, ALCOHOL FOAM.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA
& FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:THERMAL DECOMPOSITION PRODUCTS MAY
INCLUDE HCL AND PHOSGENE .

Spill Release Procedures:TAKE UP WITH ABSORBENT MATERIAL. VENTILATE
AREA. ELIMINATE ALL IGNITION SOURCES.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:REFRIGERATE IN SEALED CONTAINER. KEEP
AWAY FROM OXIDIZERS. KEEP AWAY FROM IGNITION SOURCES. AVOID EYE OR
SKIN CONTACT. AVOID BREATHING VAPORS.
Other Precautions:NO SMOKING IN AREA OF USE. DO NOT USE IN THE GENERAL
VICINITY OF ARC WELDING, OPEN FLAMES, OR HOT SURFACES. HEAT AND/OR
UV RADIATION MAY CAUSE THR FORMATION OF HCL AND/OR PHOSGENE .

Respiratory Protection:WEAR NIOSH/MSHA APPROVED FACE MASK WITH ORGANIC
VAPOR CANISTER.
Ventilation:USE ONLY IN WELL-VENTILATED AREA.
Protective Gloves:RUBBER GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS .
Other Protective Equipment:EMERGENCY EYEWASH & DELUGE SHOWER MEETING
ANSI DESIGN CRITERIA .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.

Boiling Pt:B.P. Text:149F,65C
Melt/Freeze Pt:M.P/F.P Text:-144F,-98C
Vapor Pres:100
Vapor Density:1.10
Spec Gravity:0.790
Evaporation Rate & Reference:>1 (ETHER=1)
Solubility in Water:100
Appearance and Odor:CLEAR COLORLESS LIQUID

Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS, CHROMIC ANHYDRIDE, LEAD PERCHLORATE, PERCHLORIC
ACIDS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:HCL, PHOSGENE .

Waste Disposal Methods:COMPLY WITH ALL APPLICABLE FEDERAL, STATE, OR
LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.